column 7 of the hazardous materials table

TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. N76 For materials of not more than 25 percent active ingredient by weight, packages consisting of inner metal packagings not greater than 250 mL (8 ounces) capacity each, packed in strong outer packagings together with sufficient absorbent material to completely absorb the liquid contents are authorized and need not conform to the requirements of part 178 of this subchapter. The mixture for emulsions typically has the following composition: 60-85% ammonium nitrate; 5-30% water; 2-8% fuel; 0.5-4% emulsifier or thickening agent; 0-10% soluble flame suppressants; and trace additives. For transportation by aircraft, as an inner packaging of a combination packaging with a maximum gross mass of 30 kg when packaged as a limited quantity in accordance with 173.27(f). (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. The requirements of 173.24(g)(1) and 173.27(c) do not apply. A current copy of CGA pamphlet, CGA C-6 must be available at the facility servicing the life-saving appliance. In addition, MC 312 and DOT 412 cargo tank motor vehicles must: c. Have a MAWP or design pressure of at least 87 psig; and. 157 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.151(b)(1)(i) of this subchapter for inner packagings may be increased to 5 kg (11 pounds). Sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not subject to this subchapter provided there is no free liquid in the packet or article. The caps must not contain more than an average of twenty-five hundredths of a grain of explosive composition per cap; c. The caps must be packed inside packagings constructed of cardboard not less than 0.013-inch in thickness, metal not less than 0.008-inch in thickness, non-combustible plastic not less than 0.015-inch in thickness, or a composite blister package consisting of cardboard not less than 0.013-inch in thickness and non-combustible plastic not less than 0.005-inch in thickness that completely encloses the caps; d. The minimum dimensions of each side and each end of the cardboard packaging must be 1/8th inch in height or more; e. The number of caps inside each packaging must be limited so that not more than 10 grains of explosives composition may be packed into one cubic inch of space, and not more than 17.5 grains of the explosive composition of toy caps may be packed in any inner packaging; f. Inner packagings must be packed in outer packagings meeting PG II performance criteria; g. Toy caps may be packed with non-explosive or non-flammable articles provided the outer packagings are marked as prescribed in this paragraph; h. Toy paper caps of any kind must not be packed in the same packaging with fireworks; i. authorized by name in the Hazardous Materials Table or have been specifically authorized by name either in the Section 172.101 Hazardous Materials Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. (v) The box must be constructed from high-density polyethylene in the density range 0.950-0.962, and be capable of holding liquid when in the upright position. (h) Column 7: Special provisions. All special provision 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. Portable tank special provisions are assigned to certain hazardous materials to specify requirements that are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. For the purpose of this special provision, vehicles are self-propelled apparatus designed to carry one or more persons or goods. However, button cell batteries installed in equipment (including circuit boards) need not be considered; and, c. The shipping paper must indicate UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with equipment, as appropriate. A9 For combination packagings, if plastic bags are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. All openings must be closed with gasketed blank flanges or vapor tight threaded closures. 372 This entry applies to asymmetric capacitors with an energy storage capacity greater than 0.3 Wh. See Batteries, dry, sealed, n.o.s. in the 172.101 Hazardous Materials Table (HMT) of this part for transportation requirements for nickel-metal hydride batteries transported by other modes and for nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel. The letter codes are placed in front of the number codes (for example, "A29"). (d) Used or spent battery exception. package). B68 Sodium must be in a molten condition when loaded and allowed to solidify before shipment. The numbers and letters in the special provisions column are referred to in 49 CFR 172.102 with an explanation of their meanings. If you would like to comment on the current content, please use the 'Content Feedback' button below for instructions on contacting the issuing agency. The Packing Group assigned will be II or III, according to the classification criteria for either Class 3 or Division 4.1, as appropriate, applied to the base material. 78 This entry may not be used to describe compressed air which contains more than 23.5 percent oxygen. See UN1210, UN1263, UN1266, UN3066, UN3469, and UN3470. B53 Packagings must be made of either aluminum or steel. 370 This entry also applies to ammonium nitrate with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any added substance, that gives a positive result when tested in accordance with Test Series 2 of the UN Manual of Tests and Criteria, Part I (IBR; see 171.7 of this subchapter). Note 1: Based on maximum lading pressure of 1 psig at top of cargo tank. The Office of the Federal Register publishes documents on behalf of Federal agencies but does not have any authority over their programs. [Amdt. B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of 172.302(b). (a) The Hazardous Materials Table . 149 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to 5 L (1.3 gallons). This web site is designed for the current versions of Hazardous materials necessary for the safe and proper operation of the cargo transport unit (e.g., fire extinguishing systems and air conditioning systems), must be properly secured to or installed in the cargo transport unit and are not otherwise subject to this subchapter. These provisions apply only to bulk packagings. Packagings of other material constructed with a small amount of metal must be designed such that the hazardous material does not contact the metal. Primary receptacles must be further packed in non-specification bulk outer packagings such as cubic yard boxes, plastic rigid-wall bulk containers, dump trailers, and roll-off containers. The unintended errors are summarized below. Non-specification bulk bins are authorized. An unused lighter or a lighter that is cleaned of residue and purged of vapors is not subject to the requirements of this subchapter. TP36 For material assigned this portable tank special provision, portable tanks used to transport such material may be equipped with fusible elements in the vapor space of the portable tank. A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. This is an automated process for When used for purposes such as sterilization, inner packagings of peroxyacetic acid, stabilized, classified as UN 3107 Organic peroxide type E, liquid or UN 3109 Organic peroxide type F, liquid may be fitted with a vent consisting of hydrophobic membrane, provided: (1) Each inner packaging contains not more than 70 mL; (2) The inner packaging is designed so that the vent is not immersed in liquid in any orientation; (3) Each inner packaging is enclosed in an intermediate rigid plastic packaging with a small opening to permit release of gas and contains a buffer that neutralizes the contents of the inner packaging in the event of leakage; (4) Intermediate packagings are packed in a fiberboard box (4G) outer packaging; (5) Each outer packaging contains not more than 1.4 L of liquid; and. 8 A hazardous substance that is not a hazardous waste may be shipped under the shipping description Other regulated substances, liquid or solid, n.o.s., as appropriate. After filling, each glass inner packaging must be determined to be leak-tight by placing the glass inner packaging in a hot water bath at a temperature and for a period of time sufficient to ensure that an internal pressure equal to the vapor pressure of ethylene oxide at 55 C is achieved. TP7 The vapor space must be purged of air by nitrogen or other means. will also bring you to search results. B5 Only ammonium nitrate solutions with 35 percent or less water that will remain completely in solution under all conditions of transport at a maximum lading temperature of 116 C (240 F) are authorized for transport in the following bulk packagings: MC 307, MC 312, DOT 407 and DOT 412 cargo tanks with at least 172 kPa (25 psig) design pressure. The tank car specification may be marked to indicate a test pressure of 13.79 Bar (200 psig). Insulating materials may not promote corrosion to steel when wet. The receptacle must contain no hazardous materials other than the liquid nitrogen which must be fully absorbed in a porous material in the receptacle. A copy of the approval must accompany each shipment. TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. We recommend you directly contact the agency responsible for the content in question. Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. For criteria in determining what is a new lighter design, see 173.308(b)(1). Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. (i) These provisions apply to the transportation of hazardous materials in UN portable tanks. For example, nickel-metal hydride batteries transported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). Table I - Maximum Ambient Temperature - Gasoline. b. Portable tanks containing solidified methacrylic acid must not be reheated during transportation. These substances must satisfy the criteria for classification as an ammonium nitrate emulsion of Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see 171.7 of this subchapter), and may not be classified and transported unless approved by the Associate Administrator. An installed inflation cylinder that requires recharging must be filled in accordance with 173.301(l). This entry applies to machinery or apparatus containing hazardous materials as a residue or as an integral element of the machinery or apparatus. TP28 A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Except for transportation by aircraft, in palletized loads, a pallet box or unit load device (e.g. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. A Shipper of a hazardous material is responsible for its classification and packaging prior to offering it for shipment to a Carrier. (v) UN and IM portable tank codes/special provisions. The lithium batteries must meet the requirements of 173.185(a) and contain the necessary systems to prevent overcharge and over discharge between the batteries. An important, but often overlooked, requirement for the safe and regulatory compliant transportation of a HazMat is an understanding of the special provisions in column 7 of the Hazardous Materials Table. 16 This description applies to smokeless powder and other solid propellants that are used as powder for small arms and have been classed as Division 1.3C, 1.4C and Division 4.1 in accordance with 173.56 of this subchapter. Transport vehicles must be vented to prevent accumulation of vapors at a poisonous or flammable concentration. Pressing enter in the search box Samples taken at random must withstand the prescribed tests without breakage or leakage. If you have questions or comments regarding a published document please With less than 25 percent but not less than 10 percent formaldehyde, must be described as UN3334, Aviation regulated liquid, n.o.s. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. A8 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with cushioning material in tightly closed metal receptacles before packing in outer packagings. (7) The design type of the article must be subjected to the following test. will bring you to those results. b. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. Batteries must be securely cushioned and packed to prevent shifting which could loosen terminal caps or reorient the terminals to produce short circuits. Net weight of contents in fiberboard boxes may not exceed 29 kg (64 pounds). Each transport unit must be leakproof when used as bulk packaging. 151 If this material meets the definition of a flammable liquid in 173.120 of this subchapter, a FLAMMABLE LIQUID label is also required and the basic description on the shipping paper must indicate the Class 3 subsidiary hazard. A portable tank may be offered for transport after the date of expiry of the last lining inspection for a period not to exceed three months for purposes of performing the next required test or inspection, after emptying but before cleaning. A56 Radioactive material with a subsidiary hazard of Division 4.2, Packing Group I, must be transported in Type B packages when offered for transportation by aircraft. g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request. (vi) Except when an organic peroxide is authorized under 173.225(g), if a hazardous material is not assigned a portable tank T Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator. Microsoft Edge, Google Chrome, Mozilla Firefox, or Safari. e. A description to which special provision 170 or TP7 is assigned in Column 7 of the 172.101 Hazardous Materials Table, and therefore requires air to be eliminated from the package vapor space by nitrogen or other means, must not be offered for transportation under this description. 109 Rocket motors must be nonpropulsive in transportation unless approved in accordance with 173.56 of this subchapter. B23 Tanks must be made of steel that is rubber lined or unlined. (4) A code containing the letters IB or IP refers to a special provision that applies only to transportation in IBCs. When phlegmatized with water and inorganic inert material, the content of urea nitrate must not exceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. (9) W codes. TP10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority, is required. metal other than steel or aluminum (50N). The device must be in the vapor space when the tank is filled under maximum filling conditions. When a special provision specifies packaging or packaging requirements - The coal tar pitch compound must be in a solid mass during transportation. This entry does not apply to capacitors that by design maintain a terminal voltage (e.g., asymmetrical capacitors.). A53 Refrigerating machines and refrigerating machine components are not subject to the requirements of this subchapter when containing less than 12 kg (26.4 pounds) of a non-flammable gas or when containing 12 L (3 gallons) or less of ammonia solution (UN2672) (see 173.307 of this subchapter). The pressure relief device must be preceded by a frangible disk in accordance with the requirements in 178.275(g)(3) of this subchapter to prevent crystallization of the product in the pressure relief device. B47 Each tank may have a reclosing pressure relief device having a start-to-discharge pressure setting of 310 kPa (45 psig). Transportation of these packages also requires the door of each van trailer to be marked with Warning trailer may contain chemical vapor. This training must be documented in training records required by 172.704(d). d. Receptacles containing adsorbed or absorbed ammonia shall meet the following conditions: (1) Receptacles shall be made of a material compatible with ammonia as specified in ISO 11114-1:2012(E) and ISO 11114-1:2012/Amd 1:2017(E) (IBR, see 171.7 of this subchapter); (2) Receptacles and their means of closure shall be hermetically sealed and able to contain the generated ammonia; (3) Each receptacle shall be able to withstand the pressure generated at 85 C (185 F) with a volumetric expansion no greater than 0.1%; (4) Each receptacle shall be fitted with a device that allows for gas evacuation once pressure exceeds 15 bar (1500 kPa) without violent rupture, explosion or projection; and. If a package contains both lithium metal batteries and lithium ion batteries packed with and contained in equipment, the package must be marked as required for both battery types.

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